What Are the Rules for Assigning Oxidation Numbers?

Redox Reactions and Electrochemistry

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Electrochemical reactions involve the transfer of electrons . Mass and charge are conserved when balancing these reactions, but you need to know which atoms are oxidized and which atoms are reduced during the reaction. Oxidation numbers are used to keep track of how many electrons are lost or gained by each atom. These oxidation numbers are assigned using the following rules.

Rules for Assigning Oxidation Numbers

  • The convention is that the cation is written first in a formula, followed by the anion . For example, in NaH, the H is H-; in HCl, the H is H+.
  • The oxidation number of a free element is always 0. The atoms in He and N 2 , for example, have oxidation numbers of 0.
  • The oxidation number of a monatomic ion equals the charge of the ion. For example, the oxidation number of Na + is +1; the oxidation number of N 3- is -3.
  • The usual oxidation number of hydrogen is +1. The oxidation number of hydrogen is -1 in compounds containing elements that are less ​ electronegative than hydrogen, as in CaH 2 .
  • The oxidation number of oxygen in compounds is usually -2. Exceptions include OF 2 because F is more electronegative than O, and BaO 2 , due to the structure of the peroxide ion, which is [O-O] 2- .
  • The oxidation number of a Group IA element in a compound is +1.
  • The oxidation number of a Group IIA element in a compound is +2.
  • The oxidation number of a Group VIIA element in a compound is -1, except when that element is combined with one having a higher electronegativity. The oxidation number of Cl is -1 in HCl, but the oxidation number of Cl is +1 in HOCl.
  • The sum of the oxidation numbers of all of the atoms in a neutral compound is 0.
  • The sum of the oxidation numbers in a polyatomic ion is equal to the charge of the ion. For example, the sum of the oxidation numbers for SO 4 2- is -2.
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Chem 115 POGIL Worksheet - Week #6 Oxidation Numbers, Redox Reactions, Solution Concentration, Titrations, First Law, and Enthalpy

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Which rule for assigning oxidation numbers is correct? Hydrogen is usually –1. Oxygen is usually –2 A pure group 1 element is +1 A monatomic ion is 0

Guest

Oxygen with an oxidation number -2 is the correct oxidation number

Further explanation

The formula for determining Oxidation Numbers in general:

  • 1. The number of oxidation of single element atoms = 0. Examples of Ar, Mg, Cu, Fe, N₂, O₂, etc. = 0

Group IA (Li, Na, K, Rb, Cs, and Fr): +1

Group IIA (Be, Mg, Ca, Sr and Ba): +2

H in compound = +1, except metal hydride compounds (Hydrogen which binds IA or IIA groups) oxidation number H = -1, for example, LiH, MgH₂, etc.

  • 2. Oxidation number O in compound = -2, except OF2 = + 2 and in peroxide (Na₂O₂, BaO₂) = -1 and superoxide, for example KO₂ = -1/2.
  • 3 The oxidation number in a non-filled compound = 0,

The total amount of oxidation in ion = ion charge, Example NO₃⁻ = -1

If we see the choice of answers

  • 1. Hydrogen is usually –1 .

This statement is wrong because generally the value of H is +1 except for the Hydride metal

  • 2. Oxygen is usually –2

This statement is true , except the oxygen content of OF2, peroxide and superoxide compounds

  • 3. A pure group 1 element is +1

In the form of a single or pure element, all the classes of oxidation are 0, so this statement is wrong

  • 4. A monatomic ion is 0

Monoatomic ions consist of one ion atom is composed of several atoms called polyatomic ions

Monoatomic ion is dependent on the ion, such as H + oxidation +1, Ca2 + oxidation +2 etc. So this statement is wrong

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